Mr Sani Hamzat, the Sokoto State Sector Commander of Federal Road Safety Corp (FRSC) said the crash occurred on Wednesday.
Hamzat said all the victims were evacuated to hospital by road marshals.
Meanwhile, another accident involving two cars had claimed the life of one person on Sokoto-Gusau road.
The sector commander attributed the crashes to over speeding and dangerous driving and urged motorists respect traffic rules and regulations.
Hamzat advised motorists to always ensure that their vehicles, screens and tyres were in perfect condition before putting the vehicles on road.